"Hypothesis Of Molecular Vortices. In thermodynamics as well as in other branches of molecular physics, the laws of phenomena have to a certain extent been anticipated, and their investigation facilitated, by the aid of hypotheses as to occult molecular structures and motions with which such phenomena are assumed to be connected. The hypothesis which has answered that purpose in the case of thermodynamics, is called that of "molecular vortices," or otherwise, the "centrifugal theory of elasticity."

“It is possible to express the laws of thermodynamics in the form of independent principles, deduced by induction from the facts of observation and experiment, without reference to any hypothesis as to the occult molecular operations with which the sensible phenomena may be conceived to be connected; and that course will be followed in the body of the present treatise. But, in giving a brief historical sketch of the progress of thermodynamics, the progress of the hypothesis of thermic molecular motions cannot be wholly separated from that of the purely inductive theory.”

“In theoretical science, the question is—What are we to think? and when a doubtful point arises, for the solution of which either experimental data are wanting, or mathematical methods are not sufficiently advanced, it is the duty of philosophic minds not to dispute about the probability of conflicting suppositions, but to labour for the advancement of experimental inquiry and of mathematics, and await patiently the time when they shall be adequate to solve the question.”

“Discrepancy between theory and practice, which in sound physical and mechanical science is a delusion, has a real existence in the minds of men; and that fallacy, through rejected by their judgments, continues to exert and influence over their acts.”

“A physical theory, like an abstract science, consists of definitions and axioms as first principles, and of propositions, their consequences; but with these differences:—first, That in an abstract science, a definition assigns a name to a class of notions derived originally from observation, but not necessarily corresponding to any existing objects of real phenomena, and an axiom states a mutual relation amongst such notions, or the names denoting them; while in a physical science, a definition states properties common to a class of existing objects, or real phenomena, and a physical axiom states a general law as to the relations of phenomena; and, secondly,—That in an abstract science, the propositions first discovered are the most simple; whilst in a physical theory, the propositions first discovered are in general numerous and complex, being formal laws, the immediate results of observation and experiment, from which the definitions and axioms are subsequently arrived at by a process of reasoning differing from that whereby one proposition is deduced from another in an abstract science, partly in being more complex and difficult, and partly in being to a certain extent tentative, that is to say, involving the trial of conjectural principles, and their acceptance or rejection according as their consequences are found to agree or disagree with the formal laws deduced immediately from observation and experiment.”

“But in practical science, the question is—What are we to do?—a question which involves the necessity for the immediate adoption of some rule of working. In doubtful cases, we cannot allow our machines and our works of improvement to wait for the advancement of science; and if existing data are insufficient to give an exact solution of the question, that approximate solution must be acted upon which the best data attainable show to be the most probable. A prompt and sound judgment in cases of this kind is one of the characteristics of a Practical Man in the right sense of that term.”

“Science Of Energetics. Although the mechanical hypothesis just mentioned may be useful and interesting as a means of anticipating laws, and connecting the science of thermodynamics with that of ordinary mechanics, still it is to be remembered that the science of thermodynamics is by no means dependent for its certainty on that or any other hypothesis, having been now reduced, to a system of principles, or general facts, expressing strictly the results of experiment as to the relations between heat and motive power. In this point of view the laws of thermodynamics may be regarded as particular cases of more general laws, applicable to all such states of matter as constitute Energy, or the capacity to perform work, which more general laws form the basis of the science of energetics, — a science comprehending, as special branches, the theories of motion, heat, light, electricity, and all other physical phenomena.”